Product ID:PLBA2-2Y CUSTOM PLASMA STANDARD, 1,000 PPM (SUPDAT)
MSDS Date:04/15/1996
FSC:6810
NIIN:00N074896
MSDS Number: CCSKK

SPEX INDUSTRIES INC

203 NORCROSS AVE
METUCHEN, NJ 08840
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 908-549-7144

Preparer: SUSHA RAMANO

Cage: 07958

SPEX INDUSTRIES INC

EDISON, NJ 08820-3012 US

Telephone: 908-549-7144

Cage: 07958

(ORAL,

CAS: 7697-37-2

RTECS: QU5775000

Fraction By Weight: 2-5%

OSHA PEL 2 PPM

ACGIH TLV: 2 PPM; 4 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

0.14-1.4

CAS: 513-77-9

RTECS: CQ8600000

Fraction By Weight: <1.4%

OSHA PEL 5 MG/M3 BA

ACGIH TLV: 2 MG/M3 BA

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 90-97%

OSHA PEL N/K

ACGIH TLV: N/K

MATLS SUCH AS ALCOHOL, WOOD, TURPENTINE,

RTECS: 9999999ZZ

BASES WILL CAUSE VIOLENT SPLATTERING.

RTECS: 9999999ZZ

IN CONTACT W/EYES IT PRDCES SEV BURNS

RTECS: 9999999ZZ

THE LIQUID OR CONCENTRATED VAPOR PRDCES IMMED, SEV &

RTECS: 9999999ZZ

ULCERS & STAIN SKIN BRIGHT YELLOW OR YELLOWISH BROWN

RTECS: 9999999ZZ

EXPOSURE. INGEST OF LIQ WILL CAUSE IMMED PAIN &

RTECS: 9999999ZZ

CAUSING SPASM, INFLAMMATION & EDEMA OF LARYNX &

RTECS: 9999999ZZ

SYMPTOMS INCLUDE BURNING SENSATION, COUGHING,

RTECS: 9999999ZZ

NAUSEA & VOMITING. THIS MATERIAL IS NOT KNOWN TO

RTECS: 9999999ZZ

CARCINOGEN BY OSHA, IARC OR NTP.

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SYMPS & HLTH HAZS FOR DILUTE NITRIC
ACID ARE EXPECTED TO BE LESS SEV THAN EXPOS TO CONCENTRATED NITRIC
ACID. HOWEVER, SINCE NITRIC ACID IS IN SOLN AT 1% (OR 10,000 PPM)
OR GREATER, HLTH HAZS FOR CONCE NTRATED NITRIC ACID ARE GIVEN. THIS
SOLN MAY BE HARMFUL IF INHALED, INGESTED OR CONTACTED W/SKIN OR
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: EYES. BARIUM CMPDS CAN BE POISONOUS.
SYMPS OF EXPOS TO BARIUM ARE GASTROENTERITIS, SLOW PULSE RATE, MUSC
PARALYSIS & DERMAL, NASAL & BRONCH IRRIT. CONCENTRATED NITRIC ACID
MAY BE FATAL IF TO O MUCH IS INHALED/ABSORBED THRU SKIN.
CONCENTRATED NITRIC ACID VAP/MIST IS IRRITANT OF EYES, MUC MEMBS &
SKIN. (ING 6)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MINUTES OCCASIONALLY
LIFTING UPPER & LOWER EYELIDS. SKIN: REMOVE CONTAMINATED CLOTHING
THEN FLUSH W/WATER FOR AT LEAST 15 MINUTES. WASH CLOTHING
THOROUGHLY BEFORE R EUSE. INHAL: MOVE TO FRESH AIR. INGEST:DO NOT
INDUCE VOMITING. GET IMMED MED HELP. IF PATIENT IS CONSCIOUS, GIVE
LARGE QUANTITIES OF WATER OR MILK. IF IRRITATION CONTINUES, GET MED
ATTN IMMED.

Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONCENTRATED HNO*3 IS NOT COMBUST BUT IS
STRONG OXIDIZER & ITS HEAT OF RXN W/REDUCING AGENTS OR COMBUSTS MAY
CAUSE IGNIT. CAN REACT W/METALS TO RELEASE (SUPDAT)

Spill Release Procedures:VENT AREA. DILUTE SPILL W/WATER & NEUTRALIZE
W/SODA ASH, LIMESTONE, ETC. WIPE UP & PUT INTO A SEALED CNTNR FOR
PROPER DISP. WASH SPILL SITE OFF W/WATER AFTER MATL PICK UP IS
COMPLETE. WEAR CHEM RESIST GLASSES, GLOVES & CLTHG. WEAR NIOSH
APPRVD RESP.
Neutralizing Agent:NEUTRALIZE WITH SODA ASH, LIMESTONE, ETC.

Handling and Storage Precautions:CONCENTRATED NITRIC ACID WILL ATTACK
SOME FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM TEMP. KEEP
TIGHTLY SEALED WHEN NOT IN USE.
Other Precautions:WARNING: IRRITANT, OXIDIZER, CORROSIVE. AVOID
INHALATION, INGESTION AND CONTACT WITH EYES AND SKIN. WASH
CAREFULLY AFTER USE.

Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR.
Ventilation:USE IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 14)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR CHEMICAL RESISTANT CLOTHING. LAB COAT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: BARIUM IN 2% NITRIC ACID. EXPLO HAZ:
FLAMMABLE HYDROGEN GAS. CONCENTRATED HNO*3 REACTS EXPLOSIVELY
W/COMBUST ORGANIC OR READILY OXIDIZABLE MATLS SUCH AS ALCOHOL,
WOOD, TURPEN TINE, METAL POWDERS, HYDROGEN SULFIDE, ETC.

Spec Gravity:APPROX 1
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT WITH AN ACRID ODOR.

Stability Indicator/Materials to Avoid:YES
CONCENTRATED HNO*3 IS A POWERFUL OXIDIZING AGENT. IT REACTS EXPLOSIVELY
W/COMBUST ORGANIC OR READILY OXIDIZABLE (ING 4)
Stability Condition to Avoid:STABLE UNDER NORMAL STORAGE & USE.
ELEVATED TEMPS MAY CAUSE CONTAINERS TO BURST & LIBERATE TOXIC
OXIDES OF NITROGEN.
Hazardous Decomposition Products:WILL RELEASE TOXIC NITROGEN OXIDE
FUMES AND VAPORS.

Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE
DISPOSAL AGENCY FOR FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.